An evaluation of IASI-NH₃ with ground-based Fourier transform infrared spectroscopy measurements

Enrico Dammers (1) , Mathias Palm (2) , Martin van Damme (1, 3) , Corinne Vigouroux (4) , Dan Smale (5) , Stephanie Conway (6) , Geoffrey C. Toon (7) , Nicholas Jones (8) , Eric Nussbaumer (9) , Thorsten Warneke (2) , Christof Petri (2) , Lieven Clarisse (3) , Cathy Clerbaux (3, 10) , Christian Hermans (4) , Erik Lutsch (6) , Kim Strong (11) , James W. Hannigan (9) , Hideaki Nakajima (12) , Isamu Morino (12) , Beatriz Herrera (13) , Wolfgang Stremme (13) , Michel Grutter (13) , Martijn Schaap (14) , Roy J. Wichink Kruit (15) , Justus Notholt (2) , Pierre-François Coheur (3) , Jan Willem Erisman (1, 16)

1 FALW - Faculty of Earth and Life Sciences [Amsterdam]
2 IUP - Institut für Umweltphysik [Bremen]
3 Spectroscopie de l'atmosphère, Service de Chimie Quantique et Photophysique
4 BIRA-IASB - Belgian Institute for Space Aeronomy / Institut d'Aéronomie Spatiale de Belgique
5 NIWA - National Institute of Water and Atmospheric Research [Lauder]
6 University of Toronto
7 JPL - Jet Propulsion Laboratory
8 CAC - Centre for Atmospheric Chemistry [Wollongong]
9 NCAR - National Center for Atmospheric Research [Boulder]
10 TROPO - LATMOS
11 Department of Physics [Toronto]
12 NIES - National Institute for Environmental Studies
13 Centro de Ciencias de la Atmosfera [Mexico]
14 TNO Climate, Air and Sustainability [Utrecht]
15 RIVM - National Institute for Public Health and the Environment [Bilthoven]
16 Louis Bolk Institute

Global distributions of atmospheric ammonia (NH₃) measured with satellite instruments such as the Infrared Atmospheric Sounding Interferometer (IASI) contain valuable information on NH₃ concentrations and variability in regions not yet covered by ground based instruments. Due to their large spatial coverage and daily observations, the satellite observations have the potential to increase our knowledge of the distribution of NH₃ emissions, and associated seasonal cycles. However the observations remain poorly validated, with only a handful of available studies often using only surface observations without any vertical information. In this study, we present the first validation of the IASI-NH₃ product using ground-based Fourier Transform InfraRed (FTIR) observations. Using a recently developed consistent retrieval strategy, NH₃ concentration profiles have been retrieved using observations from nine Network for the Detection of Atmospheric Composition Change (NDACC) stations around the world between 2008–2015. We demonstrate the importance of strict spatio-temporal collocation criteria for the comparison. Large differences in the regression results are observed for changing intervals of spatial criteria, mostly due to terrain characteristics and the short lifetime of NH₃ in the atmosphere. The seasonal variations of both datasets are consistent for most sites. Correlations are found to be high at sites in areas with considerable NH₃ levels, whereas correlations are lower at sites with low atmospheric NH₃ levels close to the detection limit of the IASI instrument. A combination of the observations from all sites (N_obs = 547) give a MRD of −32.4 ± (56.3) %, a correlation r of 0.8 with a slope of 0.73. These results indicate that the IASI-NH₃ product performs better than previous upper bound estimates (-50% – +100 %).

Domaines: Physique Atmosphérique et Océanique [physics.ao-ph]

Enrico Dammers, Mathias Palm, Martin van Damme, Corinne Vigouroux, Dan Smale, et al.. An evaluation of IASI-NH₃ with ground-based Fourier transform infrared spectroscopy measurements. Atmospheric Chemistry and Physics, 2016, 16 (16), pp.10351-10368. ⟨10.5194/acp-2016-141⟩. ⟨insu-01288958⟩