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Article Dans Une Revue Ceramics International Année : 2023

Highly transparent Ce3+,Cr3+ co-doped GYAGG single crystals with enhanced persistent luminescence

Résumé

Despite significant interest in persistent luminescence materials, the focus of all recent works remains on the exploitation of materials in powder form. Here, a new point of view based on persistent luminescence in single crystals is presented. The garnet crystals [(Gd 0.67 Y 0.33) 3-x Ce x)](Al 2-y Cr y)Ga 3 O 12 and [(Gd 0.33 Y 0.67) 3-x Ce x ](Al 2-y Cr y)Ga 3 O 12 (GYAGG) codoped with Ce 3+ and different concentrations of Cr 3+ have been elaborated and their persistent luminescence properties are fully characterized within this work. The persistent luminescence of Ce 3+ , Cr 3+-codoped GYAGG single crystals is optimized due to their high optical quality, very good crystallinity and a volume effect where the whole material can be excited and charged by the excitation light. Furthermore, thanks to their transparency, robustness and homogeneity; in-depth optical spectroscopy characterization is possible, shedding light on the mechanism responsible for the afterglow.

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Chimie
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Dates et versions

insu-04043838 , version 1 (24-03-2023)

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Teresa Delgado, Daniel Rytz, Guanyu Cai, Mathieu Allix, Emmanuel Veron, et al.. Highly transparent Ce3+,Cr3+ co-doped GYAGG single crystals with enhanced persistent luminescence. Ceramics International, 2023, ⟨10.1016/j.ceramint.2023.02.249⟩. ⟨insu-04043838⟩
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