Light Zn and Cu isotope compositions recorded in ferromanganese crusts during the Cenozoic as evidence for hydrothermal inputs in South Pacific deep seawater

Bleuenn Gueguen (1) , Olivier Rouxel (2) , Yves Fouquet (2)

1 IUEM - Institut Universitaire Européen de la Mer
2 LGO - Laboratoire Géosciences Océan

This study presents a high-resolution record of Cu and Zn isotopes in four Fe-Mn crusts from the North and South Pacific oceans. North Pacific crusts were collected on the Apuupuu seamount south of the Hawaiian archipelago and South Pacific crusts were recovered near Rurutu Island in the Tahiti archipelago. Major and trace element compositions suggest that Cu and Zn in these crusts is of hydrogenous origin, i.e., precipitated from seawater, and they may therefore mirror deep seawater metal isotope. We show that Cu and Zn display different isotopic patterns between the North and the South Pacific Oceans but show similar temporal evolution within each geographical area. Copper and Zn isotope composition of both North Pacific crusts vary between 0.57 ‰ to 0.73 ‰ for δ^65/63Cu_NIST976 and 0.97 ‰ to 1.25 ‰ for δ^66/64Zn_JMC-Lyon. In contrast, South Pacific crusts show resolvable temporal variations, with Cu and Zn isotopic ratios increasing sharply over the last ∼ 6 Ma from 0.16 ‰ to 0.51 ‰ and 0.67 ‰ to 1.09 ‰ respectively. Notably, we observed a positive correlation between δ^65/63Cu_NIST976 and δ^66/64Zn_JMC-Lyon values in Fe-Mn crusts from the South Pacific. The correlation suggests mixing between two components in Fe-Mn crusts, a hydrothermal component with δ^65/63Cu_NIST976 ∼ 0.2 ‰ and δ^66/64Zn_JMC-Lyon ∼ 0.7 ‰, and a Pacific deep seawater component with δ^65/63Cu_NIST976 ∼ 0.7 ‰ and δ^66/64Zn_JMC-Lyon ∼ 1.2 ‰. These values are fractionated from modern dissolved Cu and Zn by a factor of -0.3 ‰ and 0.5 ‰ respectively. We suggest that the deep Southern Pacific Ocean received sustained hydrothermal input during the last 6 Ma, which was recorded in the Cu and Zn isotope composition of Fe-Mn crusts precipitated thousands of kilometers away. Our study highlights that hydrothermal venting may be a significant source of Cu and Zn in the deep oceans despite their extensive precipitation within hydrothermal vent fields. We show that this source could be persistent through time, and thus, it could have a significant impact on the biogeochemical cycling of Cu and Zn in seawater which would ultimately be recorded by Fe-Mn crusts.

Mots clés: Ferromanganese crusts; Copper isotopes; Zinc isotopes; hydrothermal inputs

Domaines: Planète et Univers [physics]; Sciences de la Terre

Bleuenn Gueguen, Olivier Rouxel, Yves Fouquet. Light Zn and Cu isotope compositions recorded in ferromanganese crusts during the Cenozoic as evidence for hydrothermal inputs in South Pacific deep seawater. Geochimica et Cosmochimica Acta, 2022, 333, pp.136-152. ⟨10.1016/j.gca.2022.06.038⟩. ⟨insu-03868832⟩