Skip to Main content Skip to Navigation
Journal articles

Measurement report: Evolution and distribution of NH3 over Mexico City from ground-based and satellite infrared spectroscopic measurements

Abstract : Ammonia (NH3) is the most abundant alkaline compound in the atmosphere, with consequences for the environment, human health, and radiative forcing. In urban environments, it is known to play a key role in the formation of secondary aerosols through its reactions with nitric and sulphuric acids. However, there are only a few studies about NH3 in Mexico City. In this work, atmospheric NH3 was measured over Mexico City between 2012 and 2020 by means of groundbased solar absorption spectroscopy using Fourier transform infrared (FTIR) spectrometers at two sites (urban and remote). Total columns of NH3 were retrieved from the FTIR spectra and compared with data obtained from the Infrared Atmospheric Sounding Interferometer (IASI) satellite instrument. The diurnal variability of NH3 differs between the two FTIR stations and is strongly influenced by the urban sources. Most of the NH3 measured at the urban station is from local sources, while the NH3 observed at the remote site is most likely transported from the city and surrounding areas. The evolution of the boundary layer and the temperature play a significant role in the recorded seasonal and diurnal patterns of NH3. Although the vertical columns of NH3 are much larger at the urban station, the observed annual cycles are similar for both stations, with the largest values in the warm months, such as April and May. The IASI measurements underestimate the FTIR NH3 total columns by an average of 32.2 ± 27.5 % but exhibit similar temporal variability. The NH₃ spatial distribution from IASI shows the largest columns in the northeast part of the city. In general, NH3 total columns over Mexico City exhibited an
Complete list of metadata
Contributor : Catherine Cardon Connect in order to contact the contributor
Submitted on : Saturday, May 7, 2022 - 12:07:50 PM
Last modification on : Monday, August 8, 2022 - 5:38:05 PM
Long-term archiving on: : Monday, August 8, 2022 - 6:10:26 PM


Publisher files allowed on an open archive


Distributed under a Creative Commons Attribution 4.0 International License



Beatriz Herrera, Alejandro Bezanilla, Thomas Blumenstock, Enrico Dammers, Frank Hase, et al.. Measurement report: Evolution and distribution of NH3 over Mexico City from ground-based and satellite infrared spectroscopic measurements. Atmospheric Chemistry and Physics Discussions, European Geosciences Union, 2022, pp.(Discussions). ⟨10.5194/acp-2022-217⟩. ⟨insu-03661656⟩



Record views


Files downloads