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Trimethylchlorosilane, (CH3)3SiCl: OH reaction kinetics and infrared spectrum

Abstract : Rate coefficients for the OH + (CH3)3SiCl (trimethylchlorosilane) gas-phase reaction were measured over the temperature range 295–375 K using a pulsed laser photolysis laser-induced fluorescence technique. The room temperature rate coefficient was determined to be k1(295 K) = (2.51 ± 0.13) × 10−13 cm3 molecule–1 s–1. The Arrhenius expression k1(T) = (7.06 ± 2.15) × 10−12 exp[–(992 ± 101)/T] cm3 molecule–1 s–1, where the quoted uncertainties are 2σ fit precision, describes the measured temperature dependence very well. As part of this work, the infrared spectra of CH3)3SiCl was measured.
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Submitted on : Monday, March 30, 2020 - 9:29:49 AM
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Dimitrios K Papanastasiou, François Bernard, James B Burkholder. Trimethylchlorosilane, (CH3)3SiCl: OH reaction kinetics and infrared spectrum. International Journal of Chemical Kinetics, Wiley, 2020, 52 (4), pp.221-226. ⟨10.1002/kin.21344⟩. ⟨insu-02524033⟩



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