Interactions of ammonium-smectite with volatile organic compounds from leachates

Mathieu Gautier 1 Fabrice Muller 2 Lydie Le Forestier 2
2 Biogéosystèmes Continentaux - UMR7327
ISTO - Institut des Sciences de la Terre d'Orléans - UMR7327 : UMR7327
Abstract : The percolation of water through waste landfills produces leachates with high concentrations of NH4+ which can generate NH4+-exchanged clays within geochemical barriers. These leachates also contain several volatile organic compounds (VOCs) which can interact with the clay barrier. The aim of the present study was to characterize the sorption of eight short-chain VOCs (acetonitrile, methyl tert-butyl ether, dichloromethane, benzene, phenol, ethanol, acetone and aniline) on NH4+-smectite, and to identify their sorption mechanisms. The samples treated were characterized by carbon and nitrogen elemental analysis, infrared spectroscopy, powder X-ray diffraction, and thermo-gravimetric analysis. For acetonitrile, methyl tert-butyl ether, dichloromethane and benzene, no sorption was detected. Phenol, ethanol and acetone were sorbed very weakly, through Van der Waals interactions. Aniline molecules were sorbed strongly on NH4+-smectite mainly with hydrogen bonds between aniline and interlayer water molecules. However, aniline sorption decreased the hydrophilic character of the NH4+-smectite, which may increase the permeability of the clay barrier.
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Mathieu Gautier, Fabrice Muller, Lydie Le Forestier. Interactions of ammonium-smectite with volatile organic compounds from leachates. Clay Minerals, Mineralogical Society, 2017, 52, pp.143 - 159. ⟨10.1180/claymin.2017.052.1.10⟩. ⟨insu-01508689⟩

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