TRACKING THE P–T PATH OF PRECAMBRIAN ECLOGITE USING PSEUDOSECTION, Ti-IN-QUARTZ AND Zr-IN-RUTILE THERMOBAROMETRY
Abstract
Sveconorwegian eclogite occur as a nappe within the high-grade metamorphic region in southern
Sweden, which constitutes a window into the deepest part of this Precambrian mountain belt. Distinct
microstructural domains (i.e., garnet core, garnet rim, and matrix) in a Fe-Ti-rich eclogite variety contain
abundant quartz, rutile and zircon.
A pseudosection approach was first applied and compared to results from a combination of Zr-in-rutile
and Ti-in-quartz. The pressure input used for both thermometers was first deduced for each microstructural
domain from the pseudosection. For the garnet core, Zr-in-rutile yields temperatures of 700-715°C and Ti-inquartz
~ 635°C at 7 kbar. For the garnet rim, temperatures of 760-790°C (Zr-in-rutile) and 740-890°C (Ti-inquartz)
at 12-18 kbar were calculated. Matrix rutile recorded temperatures of ~ 810°C, while quartz recorded
temperatures up to ~ 890°C. Additionally, direct combination of Ti content in quartz and Zr content in rutile
isopleths (i.e., independent from the pseudosection) yield a prograde path in nearly perfect agreement with
the one deduced from the pseudosection.
The pseudosection shows that rutile was produced by continuous breakdown of ilmenite during the early
stages of prograde metamorphism, a reaction that ran to completion at ~ 730°C. Most rutile grains in garnet
rim and matrix are interpreted to subsequently form by recrystallization of smaller matrix grains. However,
they generally do not record the peak-P temperatures and instead range mostly between 775 and 815°C,
interpreted as a result of more efficient recrystallization during a dehydration reaction (progressive
replacement of hornblende by clinopyroxene).
This study illustrates that both Zr-in-rutile and Ti-in-quartz thermometry cannot only robustly constrain a
prograde evolution, but when combined with a pseudosection model can also yield information on
recrystallization processes. In fact, the combination of these three methods provides an unrivalled tool for
petrologic interpretation.
The variation in Ti concentration in quartz is small regardless of crystal size. This P–T path reach very
high temperatures (up to 875°C) with a high dP/dT ratio, both during prograde and retrograde histories. The
steep P–T path, together with preservation of garnet growth zoning, symplectitic textures and the lack of
significant Ti diffusion in quartz is consistent with a short residence time at high-temperature, implying
unusual fast burial and exhumation of the eclogite-bearing nappe.
Domains
Mineralogy
Origin : Files produced by the author(s)