R. Atkinson, Kinetics and mechanisms of the gas-phase reactions of the hydroxyl radical with organic compounds under atmospheric conditions, Chemical Reviews, vol.86, issue.1, pp.69-20110, 1986.
DOI : 10.1021/cr00071a004

R. Atkinson, Atmospheric chemistry of VOCs and NOx, Atmospheric Environment, vol.34, issue.12-14, pp.2063-210100460, 2000.
DOI : 10.1016/S1352-2310(99)00460-4

R. Atkinson and J. Arey, Atmospheric Chemistry of Biogenic Organic Compounds, Accounts of Chemical Research, vol.31, issue.9, pp.574-583, 1998.
DOI : 10.1021/ar970143z

R. Atkinson and J. Arey, Gas-phase tropospheric chemistry of biogenic volatile organic compounds: a review, Atmospheric Environment, vol.37, issue.03, pp.197-21910, 2003.
DOI : 10.1016/S1352-2310(03)00391-1

R. Atkinson, S. M. Aschmann, A. M. Winer, C. , and W. P. , Rate constants for the gas phase reactions of OH radicals and O3 with pyrrole at 295 ?? 1 K and atmospheric pressure, Atmospheric Environment (1967), vol.18, issue.10, pp.2105-210710, 1984.
DOI : 10.1016/0004-6981(84)90196-3

R. Atkinson, D. L. Baulch, R. A. Cox, R. F. Jr, J. A. Kerr et al., Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry: Supplement VI. IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry, Journal of Physical and Chemical Reference Data, vol.26, issue.6, pp.1329-1499, 1997.
DOI : 10.1063/1.556010

R. Baghi, P. Durand, C. Jambert, C. Jarnot, C. Delon et al., A new disjunct eddy-covariance system for BVOC flux measurements ? validation on CO 2 and H 2 O fluxes, Atmos. Meas. Tech, vol.55194, pp.3119-313210, 2012.

B. Bonsang, C. Polle, L. , and G. , Evidence for marine production of isoprene, Geophysical Research Letters, vol.93, issue.11, pp.1129-113210, 1992.
DOI : 10.1029/92GL00083

P. D. Carlo, W. H. Brune, M. Martinez, H. Harder, R. Lesher et al., Missing OH Reactivity in a Forest: Evidence for Unknown Reactive Biogenic VOCs, Missing OH Reactivity in a Forest: Evidence for Unknown Reactive Biogenic VOCs, pp.722-725, 2004.
DOI : 10.1126/science.1094392

M. Claeys, B. Graham, G. Vas, W. Wang, R. Vermeylen et al., Formation of Secondary Organic Aerosols Through Photooxidation of Isoprene, Science, vol.303, issue.5661, pp.1173-1176, 2004.
DOI : 10.1126/science.1092805

P. K. Dasgupta, S. Dong, H. Hwang, H. Yang, and Z. Genfa, Continuous liquid-phase fluorometry coupled to a diffusion scrubber for the real-time determination of atmospheric formaldehyde, hydrogen peroxide and sulfur dioxide, Atmospheric Environment (1967), vol.22, issue.5, pp.949-96310, 1988.
DOI : 10.1016/0004-6981(88)90273-9

D. Gouw, J. Warneke, and C. , Measurements of volatile organic compounds in the earth's atmosphere using proton-transfer-reaction mass spectrometry, Mass Spectrometry Reviews, vol.38, issue.224, pp.223-257, 2007.
DOI : 10.1002/mas.20119

T. J. Dillon, M. E. Tucceri, K. Dulitz, A. Horowitz, L. Vereecken et al., N (Pyrrole): Temperature and Pressure Dependent Rate Coefficients, The Journal of Physical Chemistry A, vol.116, issue.24, pp.6051-605810, 2012.
DOI : 10.1021/jp211241x

. Zannoni, OH reactivity and concentrations of biogenic volatile organic compounds tochemical Processes (OP3) project, Atmos. Chem. Phys, vol.13, pp.9497-951410, 2013.

J. D. Fuentes, L. Gu, M. Lerdau, R. Atkinson, D. Baldocchi et al., Biogenic Hydrocarbons in the Atmospheric Boundary Layer: A Review, Bulletin of the American Meteorological Society, vol.81, issue.7, pp.1537-157510, 2000.
DOI : 10.1175/1520-0477(2000)081<1537:BHITAB>2.3.CO;2

A. Genard-zielinski, C. Boissard, C. Fernandez, C. Kalogridis, J. Lathière et al., Variability of BVOC emissions from a Mediterranean mixed forest in southern France with a focus on <i>Quercus pubescens</i>, Atmospheric Chemistry and Physics, vol.15, issue.1, pp.431-44610, 2015.
DOI : 10.5194/acp-15-431-2015

F. Giorgi, Climate change hot-spots, Geophysical Research Letters, vol.17, issue.8, pp.10-1029, 2006.
DOI : 10.1029/2006GL025734

F. Giorgi and P. Lionello, Climate change projections for the Mediterranean region, Global and Planetary Change, vol.63, issue.2-3, pp.90-104, 2008.
DOI : 10.1016/j.gloplacha.2007.09.005

F. Giorgi, E. Im, E. Coppola, N. S. Diffenbaugh, X. J. Gao et al., Higher Hydroclimatic Intensity with Global Warming, Journal of Climate, vol.24, issue.20, pp.5309-532410, 2011.
DOI : 10.1175/2011JCLI3979.1

A. Guenther, C. N. Hewitt, D. Erickson, R. Fall, C. Geron et al., A global model of natural volatile organic compound emissions, Journal of Geophysical Research, vol.93, issue.3, pp.8873-889210, 1029.
DOI : 10.1029/94JD02950

A. Guenther, T. Karl, P. Harley, C. Wiedinmyer, P. I. Palmer et al., Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature), A tmos, Chem. Phys, vol.65194, issue.6, pp.3181-321010, 2006.

R. F. Hansen, S. M. Griffith, S. Dusanter, P. S. Rickly, P. S. Stevens et al., Measurements of total hydroxyl radical reactivity during CABINEX 2009 ? Part 1: field measurements, Atmos. Chem. Phys, vol.145194, pp.2923-293710, 2014.

A. I. Hirsch, J. W. Munger, D. J. Jacob, L. W. Horowitz, and A. H. Goldstein, at Harvard Forest, Massachusetts, Journal of Geophysical Research: Atmospheres, vol.34, issue.D7, pp.12659-1266610, 1996.
DOI : 10.1029/96JD00557

R. Holzinger, E. Sanhueza, R. Von-kuhlmann, B. Kleiss, L. Donoso et al., Diurnal cycles and seasonal variation of isoprene and its oxidation products in the tropical savanna atmosphere, Global Biogeochemical Cycles, vol.28, issue.2, pp.10-1029, 1074.
DOI : 10.1029/2001GB001421

R. Holzinger, A. Lee, K. T. Paw, and U. A. Goldstein, Observations of oxidation products above a forest imply biogenic emissions of very reactive compounds, Atmos. Chem. Phys, vol.55194, pp.67-7510, 2005.
URL : https://hal.archives-ouvertes.fr/hal-00301424

T. Ingham, A. Goddard, L. K. Whalley, K. L. Furneaux, P. M. Edwards et al., A flow-tube based laser-induced fluorescence instrument to measure OH reactivity in the troposphere, Atmos. Meas. Tech, vol.25194, pp.465-47710, 2009.

D. J. Jacob, B. D. Field, E. M. Jin, I. Bey, Q. Li et al., Atmospheric budget of acetone, Journal of Geophysical Research: Atmospheres, vol.56, issue.D10, pp.5-110, 2002.
DOI : 10.1029/2001JD000694

D. J. Jacob, B. D. Field, Q. Li, D. R. Blake, J. De-gouw et al., Global budget of methanol: Constraints from atmospheric observations, Journal of Geophysical Research, vol.108, issue.D13, pp.830310-1029, 2005.
DOI : 10.1029/2004JD005172

M. E. Jenkin, A. A. Boyd, and R. Lesclaux, Peroxy Radical Kinetics Resulting from the OH-Initiated Oxidation of 1,3-Butadiene, 2,3-Dimethyl-1,3-Butadiene and Isoprene, Journal of Atmospheric Chemistry, vol.29, issue.3, pp.267-29810, 1998.
DOI : 10.1023/A:1005940332441

W. Jud, L. Fischer, E. Canaval, G. Wohlfahrt, A. Tissier et al., Plant surface reactions: an opportunistic ozone defence mechanism impacting atmospheric chemistry, Atmospheric Chemistry and Physics, vol.16, issue.1, pp.277-29210, 2016.
DOI : 10.5194/acp-16-277-2016-supplement

C. Kalogridis, V. Gros, R. Sarda-esteve, B. Langford, B. Loubet et al., Concentrations and fluxes of isoprene and oxygenated VOCs at a French Mediterranean oak forest, Atmos. Chem. Phys, vol.145194, pp.10085-1010210, 2014.

T. Karl, P. Harley, A. Guenther, R. Rasmussen, B. Baker et al., The bi-directional exchange of oxygenated VOCs between a loblolly pine (Pinus taeda) plantation and the atmosphere, Atmos. Chem. Phys, vol.55194, pp.3015-303110, 2005.
URL : https://hal.archives-ouvertes.fr/hal-00301692

T. Karl, A. Guenther, R. J. Yokelson, J. Greenberg, M. Potosnak et al., The tropical forest and fire emissions experiment: Emission, chemistry, and transport of biogenic volatile organic compounds in the lower atmosphere over Amazonia, Journal of Geophysical Research, vol.93, issue.D2, pp.1830210-1029, 2007.
DOI : 10.1029/2007JD008539

J. Kesselmeier and M. Staudt, Biogenic Volatile Organic Compounds (VOC): An Overview on Emission, Journal of Atmospheric Chemistry, vol.33, issue.1, pp.23-88, 1999.
DOI : 10.1023/A:1006127516791

J. Kesselmeier, K. Bode, L. Schäfer, G. Schebeske, A. Wolf et al., Simultaneous field measurements of terpene and isoprene emissions from two dominant mediterranean oak species in relation to a North American species, Atmospheric Environment, vol.32, issue.11, pp.1947-195310, 1998.
DOI : 10.1016/S1352-2310(97)00500-1

V. Kumar and V. Sinha, VOC???OHM: A new technique for rapid measurements of ambient total OH reactivity and volatile organic compounds using a single proton transfer reaction mass spectrometer, International Journal of Mass Spectrometry, vol.374, pp.55-63, 2014.
DOI : 10.1016/j.ijms.2014.10.012

J. Laothawornkitkul, J. E. Taylor, N. D. Paul, H. , and C. N. , Biogenic volatile organic compounds in the Earth system, New Phytologist, vol.59, issue.11, pp.27-51, 2009.
DOI : 10.1111/j.1469-8137.2009.02859.x

W. Lindinger and A. Jordan, Proton-transfer-reaction mass spectrometry (PTR???MS): on-line monitoring of volatile organic compounds at pptv levels, Chemical Society Reviews, vol.378, issue.168, pp.347-37510, 1998.
DOI : 10.1039/a827347z

Y. J. Liu, I. Herdlinger-blatt, K. A. Mckinney, M. , and S. T. , Production of methyl vinyl ketone and methacrolein via the hydroperoxyl pathway of isoprene oxidation, Atmos. Chem. Phys, vol.135194, pp.5715-573010, 2013.

J. Mao, X. Ren, L. Zhang, D. M. Van-duin, R. C. Cohen et al., Insights into hydroxyl measurements and atmospheric oxidation in a California forest, Atmos. Chem. Phys, vol.125194, pp.8009-802010, 2012.

A. Mellouki and A. R. Ravishankara, Regional Climate Variability and its Impacts in the Mediterranean Area, 2007.
DOI : 10.1007/978-1-4020-6429-6

D. B. Millet, A. Guenther, D. A. Siegel, N. B. Nelson, H. B. Singh et al., Global atmospheric budget of acetaldehyde: 3-D model analysis and constraints from in-situ and satellite observations, Atmos. Chem. Phys, vol.105194, pp.3405-342510, 2010.

D. Mogensen, S. Smolander, A. Sogachev, L. Zhou, V. Sinha et al., Modelling atmospheric OH-reactivity in a boreal forest ecosystem, Atmos. Chem. Phys, vol.115194, pp.9709-971910, 2011.

Y. Nakashima, H. Tsurumaru, T. Imamura, I. Bejan, J. C. Wenger et al., Total OH reactivity measurements in laboratory studies of the photooxidation of isoprene, Atmospheric Environment, vol.62, pp.243-247, 2012.
DOI : 10.1016/j.atmosenv.2012.08.033

Y. Nakashima, S. Kato, J. Greenberg, P. Harley, T. Karl et al., Total OH reactivity measurements in ambient air in a southern Rocky mountain ponderosa pine forest during BEACHON-SRM08 summer campaign, Atmospheric Environment, vol.85, pp.1-8, 2014.
DOI : 10.1016/j.atmosenv.2013.11.042

A. C. Nölscher, J. Williams, V. Sinha, T. Custer, W. Song et al., Summertime total OH reactivity measurements from boreal forest during HUMPPA-COPEC 2010, Atmos. Chem. Phys, vol.125194, pp.8257-827010, 2012.

A. C. Nölscher, V. Sinha, S. Bockisch, T. Klüpfel, W. et al., Total OH reactivity measurements using a new fast Gas Chromatographic Photo-Ionization Detector (GC-PID), Atmos. Meas. Tech, vol.55194, pp.2981-299210, 2012.

A. C. Nölscher, E. Bourtsoukidis, B. Bonn, J. Kesselmeier, J. Lelieveld et al., Seasonal measurements of total OH reactivity emission rates from Norway spruce in 2011, Biogeosciences, vol.10, issue.6, pp.4241-425710, 2013.
DOI : 10.5194/bg-10-4241-2013-supplement

A. C. Nölscher, T. Butler, J. Auld, P. Veres, A. Muñoz et al., Using total OH reactivity to assess isoprene photooxidation via measurement and model, Atmospheric Environment, vol.89, pp.453-463, 2014.
DOI : 10.1016/j.atmosenv.2014.02.024

S. Preunkert and M. Legrand, Towards a quasi-complete reconstruction of past atmospheric aerosol load and composition (organic and inorganic) over Europe since 1920 inferred from Alpine ice cores, Clim. Past, vol.95194, pp.1403-141610, 1403.

S. Preunkert, M. Legrand, M. M. Frey, A. Kukui, J. Savarino et al., Formaldehyde (HCHO) in air, snow, and interstitial air at Concordia (East Antarctic Plateau) in summer, Atmos. Chem. Phys, vol.155194, pp.6689-670510, 2015.
URL : https://hal.archives-ouvertes.fr/insu-01141793

R. Steinbrecher and G. S. , Intra- and inter-annual variability of VOC emissions from natural and semi-natural vegetation in Europe and neighbouring countries, Atmospheric Environment, vol.43, issue.7, pp.1380-1391, 2009.
DOI : 10.1016/j.atmosenv.2008.09.072

X. Ren, HOx concentrations and OH reactivity observations in New York City during PMTACS-NY2001, Atmospheric Environment, vol.37, issue.26, pp.3627-363710, 2003.
DOI : 10.1016/S1352-2310(03)00460-6

H. J. Rinne, A. B. Guenther, J. P. Greenberg, H. , and P. C. , Isoprene and monoterpene fluxes measured above Amazonian rainforest and their dependence on light and temperature, Atmospheric Environment, vol.36, issue.14, pp.2421-242610, 2002.
DOI : 10.1016/S1352-2310(01)00523-4

J. C. Rivera-rios, T. B. Nguyen, J. D. Crounse, W. Jud, . St et al., Conversion of hydroperoxides to carbonyls in field and laboratory instrumentation: Observational bias in diagnosing pristine versus anthropogenically controlled atmospheric chemistry, Geophysical Research Letters, vol.47, issue.20, p.10, 1002.
DOI : 10.1021/es4011064

G. W. Schade and A. H. Goldstein, Fluxes of oxygenated volatile organic compounds from a ponderosa pine plantation, Journal of Geophysical Research: Atmospheres, vol.26, issue.14, pp.3111-312310, 2001.
DOI : 10.1029/2000JD900592

K. Sindelarova, C. Granier, I. Bouarar, A. Guenther, S. Tilmes et al., Global data set of biogenic VOC emissions calculated by the MEGAN model over the last 30 years, Atmospheric Chemistry and Physics, vol.14, issue.17, pp.9317-934110, 2014.
DOI : 10.5194/acp-14-9317-2014
URL : https://hal.archives-ouvertes.fr/hal-00985526

V. Sinha, J. Williams, J. N. Crowley, and J. Lelieveld, The Comparative Reactivity Method ? a new tool to measure total OH Reactivity in ambient air, Atmos. Chem. Phys, vol.85194, pp.2213-222710, 2008.
URL : https://hal.archives-ouvertes.fr/hal-00303218

V. Sinha, J. Williams, J. Lelieveld, T. M. Ruuskanen, M. K. Kajos et al., OH Reactivity Measurements within a Boreal Forest: Evidence for Unknown Reactive Emissions, Environmental Science & Technology, vol.44, issue.17, pp.6614-662010, 1021.
DOI : 10.1021/es101780b

A. H. Steiner, A. L. Goldstein, and N. Zannoni, Biogenic VOCs, in Volatile Organic Compounds in the Atmosphere OH reactivity and concentrations of biogenic volatile organic compounds at Importance of volatile organic compounds photochemistry over a forested area in central Greece, Atmos. Environ, vol.36, issue.02, pp.82-128, 2002.

C. Warneke, R. Holzinger, A. Hansel, A. Jordan, W. Lindinger et al., Isoprene and Its Oxidation Products Methyl Vinyl Ketone, Methacrolein, and Isoprene Related Peroxides Measured Online over the Tropical Rain Forest of Surinam, Journal of Atmospheric Chemistry, vol.38, issue.2, pp.167-185101006326802432, 1023.
DOI : 10.1023/A:1006326802432

L. Whalley, D. Stone, and D. Heard, New Insights into the Tropospheric Oxidation of Isoprene: Combining Field Measurements, Laboratory Studies, Chemical Modelling and Quantum Theory, Top. Curr. Chem, vol.339, pp.55-95, 2014.
DOI : 10.1007/128_2012_359

C. Wiedinmyer, A. Guenther, P. Harley, N. Hewitt, C. Geron et al., Global Organic Emissions from Vegetation, Emiss. Atmospheric Trace Compd., Adv. Glob. Change Res, pp.115-170, 2004.
DOI : 10.1007/978-1-4020-2167-1_4

J. Williams, R. Holzinger, V. Gros, X. Xu, E. Atlas et al., Measurements of organic species in air and seawater from the tropical Atlantic, Geophysical Research Letters, vol.56, issue.17, pp.10-1029, 2004.
DOI : 10.1029/2003GL017167

A. M. Yáñez-serrano, A. C. Nölscher, J. Williams, S. Wolff, E. Alves et al., Diel and seasonal changes of biogenic volatile organic compounds within and above an Amazonian rainforest, Atmos. Chem. Phys, vol.155194, pp.3359-337810, 2015.

A. Yoshino, Y. Sadanaga, K. Watanabe, S. Kato, Y. Miyakawa et al., Measurement of total OH reactivity by laser-induced pump and probe technique???comprehensive observations in the urban atmosphere of Tokyo, Atmospheric Environment, vol.40, issue.40, pp.7869-7881, 2006.
DOI : 10.1016/j.atmosenv.2006.07.023

N. Zannoni, S. Dusanter, V. Gros, R. Sarda-esteve, V. Michoud et al., Intercomparison of two comparative reactivity method instruments inf the Mediterranean basin during summer 2013, Atmospheric Measurement Techniques, vol.8, issue.9, pp.3851-386510, 2015.
DOI : 10.5194/amt-8-3851-2015