Retrieval of near-surface sulfur dioxide (SO₂) concentrations at a global scale using IASI satellite observations

Abstract : SO₂ from volcanic eruptions is now operationally monitored from space in both ultraviolet (UV) and thermal infrared (TIR) spectral range, but anthropogenic SO₂ has almost solely been measured from UV sounders. Indeed, TIR instruments are well-known to have a poor sensitivity to the boundary layer (PBL), due to generally low thermal contrast (TC) between the ground and the air above it. Recent studies have demonstrated the capability of the Infrared Atmospheric Sounding Interferometer (IASI) to measure near-surface SO₂ locally, for specific atmospheric conditions. In this work, we develop a retrieval method allowing the inference of SO₂ near-surface concentrations from IASI measurements at a global scale. This method consists of two steps. Both are based on the computation of radiance indexes representing the strength of the SO₂ ν₃ band in IASI spectra. The first step allows retrieving the peak altitude of SO₂ and selecting near-surface SO₂. In the second step, 0–4 km columns of SO₂ are inferred using a look-up table (LUT) approach. Using this new retrieval method, we obtain the first global distribution of near-surface SO₂ from IASI-A, and identify the dominant anthropogenic hotspot sources and volcanic degassing. The 7-year daily time evolution of SO₂ columns above two industrial source areas (Beijing in China and Sar Cheshmeh in Iran) is investigated and correlated to the seasonal variations of the parameters that drive the IASI sensitivity to the PBL composition. Apart from TC, we show that humidity is the most important parameter which determines IR sensitivity to near-surface SO₂. As IASI provides twice daily global measurements, the differences between the retrieved columns for the morning and evening orbits are investigated. This paper finally presents a first intercomparison of the measured 0–4 km columns with an independent iterative retrieval method and with observations of the Ozone Monitoring Instrument (OMI).