Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VI – heterogeneous reactions with liquid substrates

M. Ammann 1 R.A. Cox 2 J.N. Crowley 3 M.E. Jenkin 4 Abdelwahid Mellouki 5 M.J. Rossi 6 J. Troe 7 T. J. Wallington 8
1 OFLB - Laboratory of Radiochemistry and Environmental Chemistry
2 Centre for Atmospheric Science [Cambridge, UK]
3 MPIC - Max-Planck-Institut für Chemie
4 Atmospheric Chemistry Services [UK]
5 ICARE - Institut de Combustion, Aérothermique, Réactivité et Environnement
6 LAC - Laboratory of Atmospheric Chemistry [Paul Scherrer Institute]
7 Institute of Physical Chemistry, University of G¨ottingen
8 System Analytics and Environmental Sciences Department
Abstract : This article, the sixth in the ACP journal series, presents data evaluated by the IUPAC Task Group on Atmospheric Chemical Kinetic Data Evaluation. It covers the heterogeneous processes involving liquid particles present in the atmosphere with an emphasis on those relevant for the upper troposphere/lower stratosphere and the marine boundary layer, for which uptake coefficients and adsorption parameters have been presented on the IUPAC website since 2009. The article consists of an introduction and guide to the evaluation, giving a unifying framework for parameterisation of atmospheric heterogeneous processes. We provide summary sheets containing the recommended uptake parameters for the evaluated processes. The experimental data on which the recommendations are based are provided in data sheets in separate appendices for the four surfaces considered: liquid water, deliquesced halide salts, other aqueous electrolytes and sulfuric acid.
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Journal articles
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M. Ammann, R.A. Cox, J.N. Crowley, M.E. Jenkin, Abdelwahid Mellouki, et al.. Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VI – heterogeneous reactions with liquid substrates. Atmospheric Chemistry and Physics Discussions, European Geosciences Union, 2013, 13, pp.8045-8228. ⟨10.5194/acp-13-8045-2013⟩. ⟨insu-01192785⟩

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