Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VI – heterogeneous reactions with liquid substrates
Abstract
This article, the sixth in the ACP journal series,
presents data evaluated by the IUPAC Task Group on Atmospheric
Chemical Kinetic Data Evaluation. It covers the
heterogeneous processes involving liquid particles present in
the atmosphere with an emphasis on those relevant for the
upper troposphere/lower stratosphere and the marine boundary
layer, for which uptake coefficients and adsorption parameters
have been presented on the IUPAC website since
2009. The article consists of an introduction and guide to the
evaluation, giving a unifying framework for parameterisation
of atmospheric heterogeneous processes. We provide summary
sheets containing the recommended uptake parameters
for the evaluated processes. The experimental data on which
the recommendations are based are provided in data sheets
in separate appendices for the four surfaces considered: liquid
water, deliquesced halide salts, other aqueous electrolytes
and sulfuric acid.
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