Rate coefficients for the reaction of ozone with 2- and 3-carene

Abstract : The rate coefficients for the reactions of ozone with 2-carene and 3-carene have been measured at760 Torr of air and 299 ± 6 K using both absolute and relative methods. The data obtained are (in unitsof ×10−17cm3molecule−1s−1): k(2-carene) = 23.8 ± 1.0, k(3-carene) = 3.7 ± 0.2. The present work supple-ments the kinetic database of 2-carene and 3-carene using varied conventional experimental methods.The results are compared with the literature data and discussed with respect to atmospheric chemistry.
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H Chen, Y Ren, M. Cazanau, Véronique Daële, Y. Hu, et al.. Rate coefficients for the reaction of ozone with 2- and 3-carene. Chemical Physics Letters, Elsevier, 2015, 621, pp.71-77. ⟨10.1016/j.cplett.2014.12.056⟩. ⟨insu-01103130⟩

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