Primary gold deposition linked to aqueous fluids in the Inata gold deposit (Burkina Faso) : Evidence from sulphides and fluid inclusions geochemistry
Abstract
The Inata gold deposit is hosted by metavolcano-sedimentary units that
were affected by several pre-, syn- and post-mineralization deformation
stages and greenschist-facies metamorphism during the Eburnean orogeny.
Early-D1 E-W oriented structures host anhedral pyrite of metamorphic
origin, rich in Ni, Co, As and Cu (concentrations measured
by in-situ LA-ICPMS). The Au/Ag ratio of this early pyrite generation
is very low (<0.05). During the ore stage (D2, N-S oriented shearzones),
sulphides occur as euhedral pyrite and arsenopyrite, characterised
by high Au/Ag ratios (>1). Concentrations of arsenopyrite are highest
close to quartz-ankerite-albite veins and decrease gradually with
distance, whereby pyrite becomes the dominant sulphide furthest from
the veins. Visible gold is essentially found within fractures crosscutting
sulphides associated to late stage transpressive D3 structures. This gold
is interpreted to be the result of remobilization of early, disseminated
gold, related to the D2 ore stage.
Analyses of fluid inclusions (FI) revealed different H2O/CO2 ratios as
well as D values of H2O for each deformation stage. Fluid geochemistry,
obtained by in-situ LA-ICPMS analysis of FI, allowed distinguishing
different fluid compositions. Early D2 ore-stage fluids are characterized
by low salinities, low CO2, and low K and Ca concentrations,
and are rich in B, Ag, Pb, As and REE. Zones in quartz veins containing
these aqueous fluids are also marked by higher 18O values (>15‰)
than D1, late D2 and D3 related quartz veins. In contrast, late D3 fluids
related to remobilization are rich in CO2 and K and do not contain most
of the latter trace elements. Trapping conditions of FI related to early
D2 stage are of 410 (30) °C and 1.75 (0.25) kbar, whereas those related
to the D3 event where trapped from 320 to 360°C and between 1.1
to 1.5 kbar. The Inata gold deposit thus represents a very rare example
where nearly pure aqueous mineralizing fluids are documented.