Inorganic calcite precipitation in tartare karstic spring (Lazio, central Italy) : field measurement and theoretical prediction on depositional rates, Environmental Geology, vol.41, pp.305-313, 2001. ,
Hydrochemical environments of carbonate terrains, Water Resources Research, vol.10, issue.2, pp.949-957, 1973. ,
DOI : 10.1029/WR009i004p00949
Precipitation kinetics ofcalcite in the system CaCO 3 - H 2 O-CO 2 : the conversion to CO 2 by the slowprocess H+ + HCO 3 -? CO 2 + H 2 O as a limiting steps, 1997. ,
Relationship between carbon dioxide in Balcarka Cave and adjacent soils in the Moravian Karst region of the Czech Republic, International Journal of Speleology, vol.41, issue.1, pp.17-28, 2012. ,
DOI : 10.5038/1827-806X.41.1.3
Partial pressures of co 2 in epikarstic zone deduced from hydrogeochemistry of permanent drips, the moravian karst, czech republic, Acta Carsologica, vol.41, pp.47-57, 2012. ,
Controls on trace element (Sr???Mg) compositions of carbonate cave waters: implications for speleothem climatic records, Chemical Geology, vol.166, issue.3-4, pp.255-269, 2000. ,
DOI : 10.1016/S0009-2541(99)00216-8
Karst hydrogeology and geomorphology, 2007. ,
DOI : 10.1002/9781118684986
CO2 outgassing and calcite precipitation in Falling Spring Creek, Virginia, U.S.A., Chemical Geology, vol.62, issue.3-4, pp.251-262, 1986. ,
DOI : 10.1016/0009-2541(87)90090-8
Using hydrogeology to identify the source of groundwater to Montezuma Well, a natural spring in Central Arizona, USA: part 1, Environmental Earth Sciences, vol.15, issue.12, pp.1821-1835, 2012. ,
DOI : 10.1007/s12665-012-1801-1
Characterising the main karst aquifers of the Alvand basin, northwest of Zagros, Iran, by a hydrogeochemical approach, Hydrogeology Journal, vol.15, issue.5-6, pp.787-799, 2005. ,
DOI : 10.1007/s10040-004-0350-4
The analystical control of anti-corrosion water treatment, Journal of American Waterworks Association, vol.28, pp.1500-1521, 1936. ,
Geochemistry and stable isotopic composition of tufa waters and precipitates from the Interlake Region, Manitoba, Canada: Constraints on groundwater origin, calcitization, and tufa formation, Chemical Geology, vol.260, issue.3-4, pp.221-233, 2009. ,
DOI : 10.1016/j.chemgeo.2008.12.024
High-resolution study on the hydrochemical variations caused by the dilution of precipitation in the epikarst spring: an example spring of Landiantang at Nongla, Mashan, China, Environmental Geology, vol.47, issue.3, pp.347-354, 2008. ,
DOI : 10.1007/s00254-007-0821-8
Seasonal, diurnal and storm-scale hydrochemical variations of typical epikarst springs in subtropical karst areas of SW China: Soil CO2 and dilution effects, Journal of Hydrology, vol.337, issue.1-2, pp.207-223, 2007. ,
DOI : 10.1016/j.jhydrol.2007.01.034
Hydrodynamic control of inorganic calcite precipitation in Huanglong Ravine, China: Field measurements and theoretical prediction of deposition rates, Geochimica et Cosmochimica Acta, vol.59, pp.3087-3097, 1995. ,
Seasonal microclimate control of calcite fabrics, stable isotopes and trace elements in modern speleothem from St Michaels Cave, Gibraltar, Geological Society, London, Special Publications, vol.336, issue.1, pp.323-344, 2010. ,
DOI : 10.1144/SP336.17
User's guide to PHREEQC A computer program for speciation, reaction-path, advectivetransport , and inverse geochemical calculations, U.S. Geological Survey Water-Resources Investigations Report, pp.95-4227, 1995. ,
Hydrogeochemical study of the Terme and Karakurt thermal and mineralized waters from Kir??ehir Area, central Turkey, Environmental Earth Sciences, vol.19, issue.2, pp.169-182, 2012. ,
DOI : 10.1007/s12665-011-1217-3
Geochemical evolution of groundwater in the unsaturated zone of a karstic massif, using the Pco 2 -SIc relationship, Journal of Hydrology, vol.430, pp.13-24, 2012. ,
Estimation of epikarst air <mml:math altimg="si1.gif" overflow="scroll" xmlns:xocs="http://www.elsevier.com/xml/xocs/dtd" xmlns:xs="http://www.w3.org/2001/XMLSchema" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://www.elsevier.com/xml/ja/dtd" xmlns:ja="http://www.elsevier.com/xml/ja/dtd" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:tb="http://www.elsevier.com/xml/common/table/dtd" xmlns:sb="http://www.elsevier.com/xml/common/struct-bib/dtd" xmlns:ce="http://www.elsevier.com/xml/common/dtd" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:cals="http://www.elsevier.com/xml/common/cals/dtd" xmlns:sa="http://www.elsevier.com/xml/common/struct-aff/dtd"><mml:mrow><mml:msub><mml:mrow><mml:mi>P</mml:mi></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mtext>CO</mml:mtext></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math> using measurements of water ??13CTDIC, cave air <mml:math altimg="si2.gif" overflow="scroll" xmlns:xocs="http://www.elsevier.com/xml/xocs/dtd" xmlns:xs="http://www.w3.org/2001/XMLSchema" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://www.elsevier.com/xml/ja/dtd" xmlns:ja="http://www.elsevier.com/xml/ja/dtd" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:tb="http://www.elsevier.com/xml/common/table/dtd" xmlns:sb="http://www.elsevier.com/xml/common/struct-bib/dtd" xmlns:ce="http://www.elsevier.com/xml/common/dtd" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:cals="http://www.elsevier.com/xml/common/cals/dtd" xmlns:sa="http://www.elsevier.com/xml/common/struct-aff/dtd"><mml:mrow><mml:msub><mml:mrow><mml:mi>P</mml:mi></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mtext>CO</mml:mtext></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math> and <mml:math altimg="si3.gif" overflow="scroll" xmlns:xocs="http://www.elsevier.com/xml/xocs/dtd" xmlns:xs="http://www.w3.org/2001/XMLSchema" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://www.elsevier.com/xml/ja/dtd" xmlns:ja="http://www.elsevier.com/xml/ja/dtd" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:tb="http://www.elsevier.com/xml/common/table/dtd" xmlns:sb="http://www.elsevier.com/xml/common/struct-bib/dtd" xmlns:ce="http://www.elsevier.com/xml/common/dtd" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:cals="http://www.elsevier.com/xml/common/cals/dtd" xmlns:sa="http://www.elsevier.com/xml/common/struct-aff/dtd"><mml:mrow><mml:mi mathvariant="normal">??</mml:mi><mml:msup><mml:mrow/><mml:mrow><mml:mn>13</mml:mn></mml:mrow></mml:msup><mml:msub><mml:mrow><mml:mtext>C</mml:mtext></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mtext>CO</mml:mtext></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math>, Geochimica et Cosmochimica Acta, vol.118, pp.1-17, 2013. ,
DOI : 10.1016/j.gca.2013.03.046
MIX2, a computer program for modeling chemical reactions in natural waters, U.S. Geological Survey Water-Resources Investigations Report, vol.61, 1975. ,
The solubilities of calcite, aragonite and vaterite in CO2-H2O solutions between 0 and 90??C, and an evaluation of the aqueous model for the system CaCO3-CO2-H2O, Geochimica et Cosmochimica Acta, vol.46, issue.6, pp.1011-1040, 1982. ,
DOI : 10.1016/0016-7037(82)90056-4
Monitoring Bunker Cave (NW Germany): A prerequisite to interpret geochemical proxy data of speleothems from this site, Journal of Hydrology, vol.409, issue.3-4, pp.682-695, 2011. ,
DOI : 10.1016/j.jhydrol.2011.08.068
Géomorphologie du karst de la Haute-Saumons, île d'Anticosti, 1989. ,
Source areas and climatic effects in carbonate groundwaters determined by saturation indices and carbon dioxide pressures, Water Resources Research, vol.7, issue.5, pp.1067-1073, 1972. ,
DOI : 10.1029/WR008i004p01067
Seasonal fluctuations in the chemistry of lime-stone springs: A possible means for characterizing carbonate aquifers, Journal of Hydrology, vol.14, issue.2, pp.93-128, 1971. ,
DOI : 10.1016/0022-1694(71)90001-1
Cave air control on dripwater geochemistry, Obir Caves (Austria): Implications for speleothem deposition in dynamically ventilated caves, Geochimica et Cosmochimica Acta, vol.69, issue.10, pp.2451-2468, 2005. ,
DOI : 10.1016/j.gca.2004.12.009
Carbonate geochemistry of vadose water recharging limestone aquifers, Journal of Hydrology, vol.54, issue.1-3, pp.195-208, 1981. ,
DOI : 10.1016/0022-1694(81)90160-8
Soil and karst aquifer hydrological controls on the geochemical evolution of speleothem-forming drip waters, Crag Cave, southwest Ireland, Journal of Hydrology, vol.273, issue.1-4, pp.51-68, 2003. ,
DOI : 10.1016/S0022-1694(02)00349-9
Seasonal Fluctuations in the Carbon Dioxide Partial Pressure in a Cave Atmosphere, Water Resources Research, vol.13, issue.4, pp.53-156, 1984. ,
DOI : 10.1029/WR020i001p00153
Carbon dioxide treatment of low density sludge: a new remediation strategy for acidic mining lakes?, Environmental Earth Sciences, vol.22, issue.3, pp.1711-1722, 2010. ,
DOI : 10.1007/s12665-009-0305-0
Storm pulse chemographs of saturation index and carbon dioxide pressure: implications for shifting recharge sources during storm events in the karst aquifer at Fort Campbell, Kentucky/Tennessee, USA, Hydrogeology Journal, vol.12, issue.2, pp.135-143, 2004. ,
DOI : 10.1007/s10040-003-0299-8
A scale for Pco 2 eq (in percent) is added above horizontal axis; a scale for HCO 3 ¯ concentration in mg/l at 13°C is added. Black line represents a constant bicarbonate concentration ,