Reactions of OH and Cl with isopropyl formate, isobutyl formate, n-propyl isobutyrate and isopropyl isobutyrate - INSU - Institut national des sciences de l'Univers Accéder directement au contenu
Article Dans Une Revue Chemical Physics Letters Année : 2014

Reactions of OH and Cl with isopropyl formate, isobutyl formate, n-propyl isobutyrate and isopropyl isobutyrate

Résumé

The rate coefficients for the reactions of OH with isopropyl formate, isobutyl formate, n-propyl isobutyrate and isopropyl isobutyrate have been determined using both absolute and relative methods. The relative rate method has been also used to measure the room temperature rate coefficient for the reaction of Cl with the same esters. In addition, a series of runs conducted on the OH-initiated oxidation of isopropyl formate, isobutyl formate and n-propyl isobutyrate showed the formation of acetone from the three reactions. The formation of propanal was also observed for n-propyl isobutyrate.
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insu-00989673 , version 1 (06-06-2014)

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Y.J. Zhang, P. Liang, Mathieu Cazaunau, Véronique Daële, Y.J. Mu, et al.. Reactions of OH and Cl with isopropyl formate, isobutyl formate, n-propyl isobutyrate and isopropyl isobutyrate. Chemical Physics Letters, 2014, 602, pp.68-74. ⟨10.1016/j.cplett.2014.04.020⟩. ⟨insu-00989673⟩
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