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Redox state during core formation on asteroid 4-Vesta

Abstract : Core formation is the main differentiation event in the history of a planet. However, the chemical composition of planetary cores and the physicochemical conditions prevailing during core formation remain poorly understood. The asteroid 4-Vesta is the smallest extant planetary body known to have differentiated a metallic core. Howardite, Eucrite, Diogenite (HED) meteorites, which are thought to sample 4-Vesta, provide us with an opportunity to study core formation in planetary embryos. Partitioning of elements between the core and mantle of a planet fractionates their isotopes according to formation conditions. One such element, silicon, shows large isotopic fractionation between metal and silicate, and its partitioning into a metallic core is only possible under very distinctive conditions of pressure, oxygen fugacity and temperature. Therefore, the silicon isotope system is a powerful tracer with which to study core formation in planetary bodies. Here we show through high-precision measurement of Si stable isotopes that HED meteorites are significantly enriched in the heavier isotopes compared to chondrites. This is consistent with the core of 4-Vesta containing at least 1 wt% of Si, which in turn suggests that 4-Vesta's differentiation occurred under more reducing conditions (ΔIW∼−4) than those previously suggested from analysis of the distribution of moderately siderophile elements in HEDs.
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Emily A. Pringle, Paul S. Savage, James Badro, Jean-Alix J-A Barrat, Frédéric Moynier. Redox state during core formation on asteroid 4-Vesta. Earth and Planetary Science Letters, Elsevier, 2013, 373, pp.75-82. ⟨10.1016/j.epsl.2013.04.012⟩. ⟨insu-00933993⟩



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