Journal articles
Absolute and relative rate constants for the reactions of OH and Cl with pentanols
Abstract : The rate constants for the reactions of OH with three pentanols have been determined in the range 267−373 K and P = 100 Torr. The data obtained were (in units of cm3molecule−1s−1): k(1-pentanol) = (6.7 ± 3.8) × 10−12 exp [(132 ± 176)/T], k(2-pentanol) = (5.2 ± 1.8) × 10−12 exp [(218 ± 116)/T], k(3-pentanol) = (5.8 ± 2.3) × 10−12 exp [(164 ± 118)/T]. The present work provides the first temperature dependence data on these reactions. In addition, using the relative rate method, the rate constants for OH and Cl with these pentanols have been measured. The results are compared with the literature data and discussed with respect to atmospheric chemistry.
Cited literature [10 references]
https://hal-insu.archives-ouvertes.fr/insu-00865542
Contributor : Nathalie Pothier <>
Submitted on : Tuesday, September 24, 2013 - 3:20:21 PM
Last modification on : Tuesday, June 2, 2020 - 10:26:08 AM
Document(s) archivé(s) le : Friday, April 7, 2017 - 2:25:45 AM
Contributor : Nathalie Pothier <>
Submitted on : Tuesday, September 24, 2013 - 3:20:21 PM
Last modification on : Tuesday, June 2, 2020 - 10:26:08 AM
Document(s) archivé(s) le : Friday, April 7, 2017 - 2:25:45 AM
Files
Pentanols_OH_Cl_CPL.pdf
Files produced by the author(s)
