Service interruption on Monday 11 July from 12:30 to 13:00: all the sites of the CCSD (HAL, Epiciences, SciencesConf, AureHAL) will be inaccessible (network hardware connection).
Skip to Main content Skip to Navigation
Journal articles

Absolute and relative rate constants for the reactions of OH and Cl with pentanols

Abstract : The rate constants for the reactions of OH with three pentanols have been determined in the range 267−373 K and P = 100 Torr. The data obtained were (in units of cm3molecule−1s−1): k(1-pentanol) = (6.7 ± 3.8) × 10−12 exp [(132 ± 176)/T], k(2-pentanol) = (5.2 ± 1.8) × 10−12 exp [(218 ± 116)/T], k(3-pentanol) = (5.8 ± 2.3) × 10−12 exp [(164 ± 118)/T]. The present work provides the first temperature dependence data on these reactions. In addition, using the relative rate method, the rate constants for OH and Cl with these pentanols have been measured. The results are compared with the literature data and discussed with respect to atmospheric chemistry.
Document type :
Journal articles
Complete list of metadata

Cited literature [10 references]  Display  Hide  Download
Contributor : Nathalie POTHIER Connect in order to contact the contributor
Submitted on : Tuesday, September 24, 2013 - 3:20:21 PM
Last modification on : Tuesday, October 12, 2021 - 5:20:45 PM
Long-term archiving on: : Friday, April 7, 2017 - 2:25:45 AM


Files produced by the author(s)




M. Lendar, A. Aissat, Mathieu Cazaunau, Véronique Daële, Abdelwahid S Mellouki. Absolute and relative rate constants for the reactions of OH and Cl with pentanols. Chemical Physics Letters, Elsevier, 2013, 582, pp.38-43. ⟨10.1016/j.cplett.2013.07.042⟩. ⟨insu-00865542⟩



Record views


Files downloads