H. A. Al-hosney, S. Carlos-cuellar, J. Baltrusaitis, and V. H. Grassian, Heterogeneous uptake and reactivity of formic acid on calcium carbonate particles: a Knudsen cell reactor, FTIR and SEM study, Physical Chemistry Chemical Physics, vol.64, issue.20, pp.3587-3595, 2005.
DOI : 10.1029/2004JD005206

M. O. Andreae, R. J. Charlson, F. Bruynseels, H. Storms, and R. Van-grieken, Internal Mixture of Sea Salt, Silicates, and Excess Sulfate in Marine Aerosols, Science, vol.232, issue.4758, 1986.
DOI : 10.1126/science.232.4758.1620

R. Arimoto, A. Hogan, P. Grube, D. Davis, and J. Webb, Major ions and radionuclides in aerosol particles from the South Pole during ISCAT-2000, Atmospheric Environment, vol.38, issue.32, pp.5473-5484, 2004.
DOI : 10.1016/j.atmosenv.2004.01.049

A. Atkinson and M. J. Whitehouse, Ammonium regeneration by Antarctic mesozooplankton: an algometric approach, Marine Biol, vol.139, pp.301-311, 2001.

I. Basile, F. E. Grousset, M. Revel, J. Petit, and P. E. Biscay, Patagonian origin of glacial dust deposited in East Antarctica (Vostok and Dome C) during glacial stages 2, 4 and 6, Patagonian origin of glacial dust deposited in East Antarctica (Vostok and Dome C) during glacial stages 2, pp.573-589, 1997.
DOI : 10.1016/S0012-821X(96)00255-5

URL : https://hal.archives-ouvertes.fr/hal-00756606

B. Bonsang, D. Martin, G. Lambert, M. Kanakidou, and L. Roulley, Vertical distribution of non methane hydrocarbons in the remote marine boundary layer, Journal of Geophysical Research, vol.156, issue.D4, pp.7313-7324, 1991.
DOI : 10.1029/90JD02539

B. Bonsang, C. Polle, and G. Lambert, Evidence for marine production of isoprene, Geophysical Research Letters, vol.93, issue.11, pp.1129-1132, 1992.
DOI : 10.1029/92GL00083

M. Briat, C. Boutron, and C. Lorius, Chlorine and sodium content of East Antarctica firn samples, J. Atmos. Res, vol.8, pp.895-901, 1974.

A. Chebbi and P. Carlier, Carboxylic acids in the troposphere, occurrence, sources, and sinks: A review, Atmospheric Environment, vol.30, issue.24, pp.4233-4249, 1996.
DOI : 10.1016/1352-2310(96)00102-1

E. Cosme, F. Hourdin, C. Genthon, and P. Martinerie, The origin of dimethylsulfide (DMS), non-sea-salt sulfate, and methanesulfonic acid (MSA) in Eastern Antarctica, D03302/1ÁD03302, 2005.

L. A. Currie, J. D. Kessler, R. A. Fletcher, and J. E. Dibb, Long range transport of biomass aerosol to Greenland: Multi-spectroscopic investigation of particles deposited in the snow, Journal of Radioanalytical and Nuclear Chemistry, vol.263, issue.2, pp.399-411, 2005.
DOI : 10.1007/s10967-005-0069-2

D. Angelis, M. Barkov, N. I. Petrov, and V. N. , Sources of continental dust over Antarctica during the last glacial cycle, Journal of Atmospheric Chemistry, vol.6, issue.D12, pp.233-244, 1992.
DOI : 10.1007/BF00115236

D. Angelis, M. Legrand, and M. , Preliminary investigations of post depositional effects on HCl, HNO 3 , and organic acids in polar firn layers, In: Ice Core Studies of Global Biogeochemical Cycles NATO ASI Series I, vol.30, pp.336-381, 1995.

D. Angelis, M. Simoes, J. C. Bonnaveira, H. Taupin, J. D. Delmas et al., Volcanic eruptions recorded in the Illimani ice core (Bolivia): 1918???1998 and Tambora periods, Atmospheric Chemistry and Physics, vol.3, issue.5, pp.1725-1741, 2003.
DOI : 10.5194/acp-3-1725-2003

URL : https://hal.archives-ouvertes.fr/hal-00328349

D. Angelis, M. Steffensen, J. P. Legrand, M. Clausen, H. B. Hammer et al., Primary aerosol (sea salt and soil dust) deposited in Greenland ice during the last climatic cycle: Comparison with east Antarctic records, Journal of Geophysical Research: Oceans, vol.100, issue.17/18, pp.26681-26698, 1997.
DOI : 10.1029/97JC01298

B. Delmonte, I. Basile-doelsch, J. Petit, A. Michard, M. Revel-rolland et al., Refining the isotopic (Sr-Nd) signature of potential source areas for glacial dust in East Antarctica, Journal de Physique IV (Proceedings), vol.107, pp.6-11, 2003.
DOI : 10.1051/jp4:20030317

F. J. Dentener, G. R. Carmichael, Y. Ahang, J. Lelieved, and P. J. Crutzen, Role of mineral aerosol as a reactive surface in the global troposphere, Journal of Geophysical Research: Atmospheres, vol.VI, issue.D17, pp.22869-22889, 1996.
DOI : 10.1029/96JD01818

J. E. Dibb and M. Arsenault, Shouldn???t snowpacks be sources of monocarboxylic acids?, Atmospheric Environment, vol.36, issue.15-16, 2002.
DOI : 10.1016/S1352-2310(02)00131-0

J. E. Dibb, R. W. Talbot, and M. H. Bergin, Soluble acidic species in air and snow at Summit, Greenland, Geophysical Research Letters, vol.99, issue.15, 1994.
DOI : 10.1029/94GL01031

F. Eisele, D. D. Davis, D. Helmigc, S. J. Oltmans, and W. Neff, Antarctic Tropospheric Chemistry Investigation (ANTCI) 2003 overview, Antarctic Tropospheric Chemistry Investigation (ANTCI) 2003 overview, pp.2749-2761, 2008.
DOI : 10.1016/j.atmosenv.2007.04.013

M. Epica-community, One to one coupling of glacial climate variability in Greenland and Antarctica, Nature, vol.444, 2006.

J. Erbland, J. Savarino, S. Morin, and M. Frey, Postdepositional processing of nitrate recorded in the Vostok ice core does not care about ice ages, Geophys. Res. Abs, vol.11, pp.2009-971, 2009.

J. Erbland, J. Savarino, S. Morin, and M. Frey, The oxygen isotope anomaly (^ 17 O) of nitrate in the Vostok ice core: insights in the possible changes in NOx oxidation pathways over the last 150 000 years, Geophys. Res. Abs, vol.11, pp.2009-975, 2009.

H. Fisher, F. Fundel, U. Ruth, B. Twarloh, A. Wegner et al., Reconstruction of millennial changes in dust emission, transport and regional sea ice coverage using the deep EPICA ice cores from the Atlantic and Indian Ocean sector of Antarctica, Earth and Planetary Science Letters, vol.260, issue.1-2, pp.340-354, 2007.
DOI : 10.1016/j.epsl.2007.06.014

Y. Gao, J. R. Anderson, and X. Hua, Dust characteristics over the North Pacific observed through shipboard measurements during the ACE-Asia experiment, Atmospheric Environment, vol.41, issue.36, pp.41-7907, 2007.
DOI : 10.1016/j.atmosenv.2007.06.060

A. Gaudichet, M. De-angelis, S. Joussaume, J. Petit, and Y. S. Korotkevich, Comments on the origin of dust in East Antarctica for present and ice age conditions, Journal of Atmospheric Chemistry, vol.212, issue.1-4, pp.129-142, 1992.
DOI : 10.1007/BF00115229

D. Grosjean, Formic acid and acetic acid: Emissions, atmospheric formation and dry deposition at two southern California locations, Atmospheric Environment. Part A. General Topics, vol.26, issue.18, 1992.
DOI : 10.1016/0960-1686(92)90343-J

C. D. Hatch, R. V. Gough, and M. A. Tolbert, Heterogeneous uptake of the C<sub>1</sub> to C<sub>4</sub> organic acids on a swelling clay mineral, Atmospheric Chemistry and Physics, vol.7, issue.16, pp.4445-4458, 2007.
DOI : 10.5194/acp-7-4445-2007

J. R. Herman, N. Krotkov, E. Celarier, D. Larko, and G. Labow, Distribution of UV radiation at the Earth's surface from TOMS-measured UV-backscattered radiances, Journal of Geophysical Research: Atmospheres, vol.101, issue.D10, 1999.
DOI : 10.1029/1999JD900062

D. Jacob, Chemistry of OH in remote clouds and its role in the production of formic acid and peroxymonosulfate, Journal of Geophysical Research, vol.101, issue.62, pp.9807-9826, 1986.
DOI : 10.1029/JD091iD09p09807

D. J. Jacob and S. C. Wofsy, Photochemistry of biogenic emissions over the Amazon forest, Journal of Geophysical Research, vol.93, issue.D2, pp.1477-1486, 1988.
DOI : 10.1029/JD093iD02p01477

J. D. Kahl, D. A. Martinez, H. Kuhns, C. I. Davidson, and J. Jaffrezo, Air mass trajectories to Summit, Greenland: A 44-year climatology and some episodic events, Journal of Geophysical Research: Oceans, vol.18, issue.15, pp.26861-26875, 1997.
DOI : 10.1029/97JC00296

P. Kaufmann, F. Fundel, H. Fischer, M. Bigler, and U. Ruth, Ammonium and non-sea salt sulfate in the EPICA ice cores as indicator of biological activity in the Southern Ocean, Quaternary Science Reviews, vol.29, issue.1-2, pp.313-323, 2010.
DOI : 10.1016/j.quascirev.2009.11.009

URL : https://hal.archives-ouvertes.fr/insu-00653377

W. C. Keene and J. N. Galloway, Organic acidity in precipitation of North America, Atmospheric Environment (1967), vol.18, issue.11, pp.2491-2497, 1984.
DOI : 10.1016/0004-6981(84)90020-9

W. C. Keene and J. N. Galloway, The biogeochemical cycling of formic and acetic acids through the troposphere: an overview of current understanding, Tellus B: Chemical and Physical Meteorology, vol.3, issue.466, pp.322-334, 1988.
DOI : 10.3402/tellusb.v40i5.15994

W. C. Keene, J. M. Lobert, P. J. Crutzen, J. R. Maben, and D. H. Scharffe, Emissions of major gaseous and particulate species during experimental burns of southern African biomass, Journal of Geophysical Research, vol.29, issue.14, 2006.
DOI : 10.1029/2005JD006319

W. C. Keene, A. Pszenny, J. Galloway, and M. Hawley, Sea-salt corrections and interpretation of constituent ratios in marine precipitation, Journal of Geophysical Research, vol.33, issue.D6, pp.6647-6658, 1986.
DOI : 10.1029/JD091iD06p06647

J. Kesselmeier and M. Staudt, Biogenic volatile compounds (VOC): an overview on emission, physiology, and ecology, J. Atmos. Chem, vol.33, pp.2-3, 1999.

P. Khare, N. Kumar, and K. W. Kumari, Atmospheric formic and acetic acids: An overview, Reviews of Geophysics, vol.19, issue.2, pp.227-248, 1999.
DOI : 10.1029/1998RG900005

B. Kim and S. Park, Transport and evolution of a winter-time Yellow sand observed in Korea, Atmospheric Environment, vol.35, issue.18, pp.3191-3201, 2001.
DOI : 10.1016/S1352-2310(00)00469-6

R. Koppman, R. Bauer, F. R. Johnen, C. Plass, and J. Rudolph, The distribution of light nonmethane hydrocarbons over the mid-Atlantic: Results of the Polarstern cruise ANT VII/1, Journal of Atmospheric Chemistry, vol.86, issue.C8, pp.215-234, 1992.
DOI : 10.1007/BF00115395

M. Kumai, Identification of Nuclei and Concentrations of Chemical Species in Snow Crystals Sampled at the South Pole, Journal of the Atmospheric Sciences, vol.33, issue.5, pp.833-841, 1976.
DOI : 10.1175/1520-0469(1976)033<0833:IONACO>2.0.CO;2

B. L. Lefer, R. W. Talbot, R. C. Harris, J. D. Bradshaw, and S. Sandholm, Enhancement of acidic gases in biomass burning impacted air masses over Canada, Journal of Geophysical Research, vol.99, issue.D1, pp.1721-1737, 1994.
DOI : 10.1029/93JD02091

M. Legrand, Chimie des neiges et glaces antarctiques: un reflet de l'environnement, 1985.
URL : https://hal.archives-ouvertes.fr/tel-00706652

M. Legrand, Sulphur derived species in polar ice: a review In: Ice Core Studies of, Global Biogeochemical cycles NATO ASI Ser, vol.30, 1995.

M. Legrand and M. De-angelis, Origins and variations of light carboxylic acids in polar precipitation, Journal of Geophysical Research: Atmospheres, vol.40, issue.D1, pp.1445-1452, 1995.
DOI : 10.1029/94JD02614

M. Legrand and M. De-angelis, Light carboxylic acids in Greenland ice: A record of past forest fires and vegetation emissions from the boreal zone, Journal of Geophysical Research: Atmospheres, vol.46, issue.D2, pp.4129-4145, 1996.
DOI : 10.1029/95JD03296

M. Legrand, C. Lorius, N. Y. Barkov, and V. N. Petrov, Vostok (Antarctica) ice core: Atmospheric chemistry changes over the last climatic cycle (160,000 years), Atmospheric Environment (1967), vol.22, issue.2, pp.317-331, 1988.
DOI : 10.1016/0004-6981(88)90037-6

M. Legrand and P. Mayewsky, Glaciochemistry of polar ice cores: A review, Reviews of Geophysics, vol.23, issue.3, pp.219-243, 1997.
DOI : 10.1029/96RG03527

URL : https://hal.archives-ouvertes.fr/insu-00502145

M. Legrand and D. Wagenbach, Impact of the Cerro Hudson and Pinatubo volcanic eruptions on the Antarctic air and snow chemistry, Journal of Geophysical Research: Atmospheres, vol.102, issue.D1, pp.1581-1596, 1999.
DOI : 10.1029/1998JD100032

M. Legrand, E. Wolff, and D. Wagenbach, Antarctic aerosol and snowfall chemistry: implications for deep Antarctic ice-core chemistry, Annals of Glaciology, vol.29, issue.1, pp.6-6, 1999.
DOI : 10.3189/172756499781821094

M. Legrand, S. Preunkert, B. Jourdain, and B. Aumont, Year-round records of gas and particulate formic and acetic acids in the boundary layer at Dumont d'Urville, coastal Antarctica, Journal of Geophysical Research: Atmospheres, vol.23, issue.47, pp.1-11, 2004.
DOI : 10.1029/2003JD003786

M. Legrand, S. Preunkert, D. Wagenbach, H. Cachier, and H. Puxbaum, A historical record of formate and acetate from a high-elevation Alpine glacier: Implications for their natural versus anthropogenic budgets at the European scale, Journal of Geophysical Research: Atmospheres, vol.40, issue.D12, p.244788, 2003.
DOI : 10.1029/2003JD003594

G. C. Littot, R. Mulvaney, R. Ro¨thlisbergerro¨thlisberger, R. Udisti, and E. W. Wolff, Comparison of analytical methods used for measuring major ions in the EPICA Dome C (Antarctica) ice core, Annals of Glaciology, vol.35, issue.1, pp.299-305, 2002.
DOI : 10.3189/172756402781817022

L. Loulergue, A. Schilt, R. Spahni, V. Masson-delmotte, T. Blunier et al., Orbital and millennial-scale features of atmospheric CH4 over the past 800,000???years, Nature, vol.77, issue.7193, pp.383-386, 2008.
DOI : 10.1038/nature06950

URL : https://hal.archives-ouvertes.fr/insu-00379657

S. Madronich and J. G. Calvert, Permutation reactions of organic peroxy radicals in the troposphere, Journal of Geophysical Research, vol.93, issue.41, pp.5697-5715, 1990.
DOI : 10.1029/JD095iD05p05697

S. Madronich, R. B. Chatfield, J. G. Calvert, G. K. Moortgat, and B. Veyret, and co-authors. 1990. A photochemical origin of acetic acid in the troposphere, Geophys. Res. Lett, issue.12, pp.17-2361

K. Matsumoto, I. Nagao, H. Tanaka, H. Miyaji, and . Iida, Seasonal characteristics of organic and inorganic species and their size distributions in atmospheric aerosols over the northwest pacific ocean, Atmospheric Environment, vol.32, issue.11, p.32, 1998.
DOI : 10.1016/S1352-2310(97)00499-8

I. Moreno-rivadeneira, Natural Variability of the Atmospheric Composition and Anthropogenic Influence in Patagonia. Contribution to the Understanding of Transport Pathways Along the Equator-Mid Latitudes-Pole Transect, 2011.

A. Ooki and M. Uematsu, Chemical interactions between mineral dust particles and acid gas during Asian dust events, D03201. DOI: 10.1029, 2005.

F. Paulot, D. Wunch, J. D. Crounse, G. C. Toon, and D. B. Millet, Importance of secondary sources in the atmospheric budgets of formic and acetic acids, Atmos. Chem. Phys, vol.11, 2011.

C. Piel, R. Weller, M. Huke, and D. Wagenbach, Atmospheric methane sulfonate and non-sea-salt sulfate records at the European Project for Ice Coring in Antarctica (EPICA) deepdrilling site in Dronning Maud Land, Antarctica, J. Geophys. Res, vol.111, pp.10-1029, 2006.

N. Preiss, M. Meliè-res, and M. Pourchet, A compilation of data on lead 210 concentration in surface air and fluxes at the air-surface and water-sediment interfaces, Journal of Geophysical Research: Atmospheres, vol.76, issue.9, pp.28847-28862, 1996.
DOI : 10.1029/96JD01836

P. Prince, A. Kleiber, P. D. Grrassian, V. H. Young, and M. A. , Reactive uptake of acetic acid on calcite and nitric acid reacted calcite aerosol in an environmental reaction chamber, Phys. Chem. Chem. Phys., vol.236, issue.16, pp.142-152, 2008.
DOI : 10.1029/2000JD000011

S. Preunkert, B. Jourdain, M. Legrand, R. Udisti, and S. Becagli, Seasonality of sulfur species (dimethyl sulfide, sulfate, and methanesulfonate) in Antarctica: Inland versus coastal regions, Journal of Geophysical Research, vol.65, issue.D22, 2008.
DOI : 10.1029/2008JD009937

URL : https://hal.archives-ouvertes.fr/insu-00381048

R. Ro¨thlisbergerro¨thlisberger, M. A. Hutterli, S. Sommer, E. W. Wolff, and R. Mulvaney, Factors controlling nitrate in ice cores: evidence from the Dome C deep ice core, J. Geophys. Res, vol.105, 2000.

U. Ruth, J. Barnola, J. Beer, M. Bigler, and T. Blunier, "EDML1": a chronology for the EPICA deep ice core from Dronning Maud Land, Antarctica, over the last 150 000 years, Climate of the Past, vol.3, issue.3, pp.475-484, 2007.
DOI : 10.5194/cp-3-475-2007-supplement

URL : https://hal.archives-ouvertes.fr/hal-00330760

J. Savarino and M. Legrand, High northern latitude forest fires and vegetation emissions over the last millennium inferred from the chemistry of a central Greenland ice core, Journal of Geophysical Research: Atmospheres, vol.20, issue.D7, pp.8267-8279, 1998.
DOI : 10.1029/97JD03748

H. B. Singh, W. Viezee, Y. Chen, J. Bradshaw, and S. Sandholm, Biomass burning influences on the composition of the remote South Pacific troposphere: analysis based on observations from PEM-Tropics-A, Atmospheric Environment, vol.34, issue.4, pp.3-5, 2000.
DOI : 10.1016/S1352-2310(99)00380-5

T. Staffelbach, A. Neftel, B. Stauffer, and D. Jacob, A record of the atmospheric methane sink from formaldehyde in polar ice cores, Nature, vol.349, issue.6310, pp.0-3, 1991.
DOI : 10.1038/349603a0

R. W. Talbot, K. M. Beecher, R. C. Harris, and W. R. Cofer, Atmospheric geochemistry of formic and acetic acids at a mid-latitude temperate site, Journal of Geophysical Research, vol.18, issue.D2, pp.1638-1652, 1988.
DOI : 10.1029/JD093iD02p01638

R. W. Talbot, M. O. Andreae, H. Berresheim, D. J. Jacob, and K. M. Beecher, Sources and sinks of formic, acetic, and pyruvic acids over central Amazonia: 2. Wet season, Journal of Geophysical Research, vol.95, issue.D10, 1990.
DOI : 10.1029/JD095iD10p16799

J. Tissari, O. Sippula, K. Vuorio, and J. Fokiniemi, Fine Particle and Gas Emissions from the Combustion of Agricultural Fuels Fired in a 20 kW Burner, Energy & Fuels, vol.22, issue.3, 2008.
DOI : 10.1021/ef700766y

R. Traversi, S. Becagli, E. Castellano, O. Cerri, and A. Morganti, Study of Dome C site (East Antartica) variability by comparing chemical stratigraphies, Microchemical Journal, vol.92, issue.1, pp.7-14, 2009.
DOI : 10.1016/j.microc.2008.08.007

G. Tuncel, N. K. Aras, and W. H. Zoller, Temporal variations and sources of elements in the South Pole atmosphere: 1. Nonenriched and moderately enriched elements, Journal of Geophysical Research, vol.183, issue.D10, pp.94-13025, 1989.
DOI : 10.1029/JD094iD10p13025

F. Vimeux, M. De-angelis, P. Ginot, O. Magand, and G. Casassa, A promising location in Patagonia for paleoclimate and paleoenvironmental reconstructions revealed by a shallow firn core from Monte San Vanlentin (Northern Patagonia Icefield, Chile), J. Geophys. Res, vol.113, p.10, 1029.

D. Voisin, M. Legrand, and N. Chaumerliac, ) and ammonia in mixed liquid-solid water clouds at the Puy de D??me mountain (France), Journal of Geophysical Research: Atmospheres, vol.19, issue.D5, pp.6817-6835, 2000.
DOI : 10.1029/1999JD900983

R. Weller, F. Traufetter, H. Fisher, H. Oerter, and C. Piel, Post depositional losses of methane sulfonate, nitrate, and chloride at the European Project of Ice Coring in Antarctica deep-drilling site in Dronning Maud Land, Antarctica, D07301. DOI: 10.1029, p.4189, 2003.

J. W. Winchester and M. Wang, Acid-base balance in aerosol components of the Asia-Pacific region, Tellus, issue.3, pp.41-323, 1989.

E. W. Wolff, H. Fisher, U. Ruth, B. Twarloh, G. C. Littot et al., Southern Ocean sea-ice extent, productivity and iron flux over the past eight glacial cycles, Nature, vol.10, issue.7083, pp.491-496, 2006.
DOI : 10.1038/nature04614

URL : https://hal.archives-ouvertes.fr/insu-00375835