V. A. Drits, E. J. Silvester, A. I. Gorshkov, and A. Manceau, Structure of synthetic monoclinic Na-rich birnessite and hexagonal birnessite; I, Results from X-ray diffraction and selected-area electron diffraction, American Mineralogist, vol.82, issue.9-10, pp.946-961, 1997.
DOI : 10.2138/am-1997-9-1012

V. A. Drits, B. Lanson, A. I. Gorshkov, and A. Manceau, Substructure and superstructure of four-layer Ca-exchanged birnessite, American Mineralogist, vol.83, issue.1-2, pp.97-118, 1998.
DOI : 10.2138/am-1998-1-210

V. A. Drits, B. Lanson, and A. C. Gaillot, Birnessite polytype systematics and identification by powder X-ray diffraction, American Mineralogist, vol.92, issue.5-6, pp.771-788, 2007.
DOI : 10.2138/am.2007.2207

URL : https://hal.archives-ouvertes.fr/hal-00193663

D. Emerson, R. E. Garen, and G. W. , Formation of Metallogenium-like structures by a manganese-oxiding fungus, Archives of Microbiology, vol.4, issue.3, pp.223-231, 1989.
DOI : 10.1007/BF00413134

J. B. Fein, A. M. Martin, and W. P. , Metal adsorption onto bacterial surfaces: development of a predictive approach, Geochimica et Cosmochimica Acta, vol.65, issue.23, pp.4267-4273, 2001.
DOI : 10.1016/S0016-7037(01)00721-9

A. Gaillot, D. Flot, V. A. Drits, A. Manceau, M. Burghammer et al., . I. Two-Layer Polytype from 800 ??C Experiment, Chemistry of Materials, vol.15, issue.24, pp.4666-4678, 2003.
DOI : 10.1021/cm021733g

URL : https://hal.archives-ouvertes.fr/hal-00106999

A. Gaillot, B. Lanson, and D. V. , Structure of Birnessite Obtained from Decomposition of Permanganate under Soft Hydrothermal Conditions. 1. Chemical and Structural Evolution as a Function of Temperature, Chemistry of Materials, vol.17, issue.11, pp.2959-2975, 2005.
DOI : 10.1021/cm0500152

URL : https://hal.archives-ouvertes.fr/hal-00106999

A. Gaillot, V. A. Drits, A. Manceau, and L. B. , Structure of the synthetic K-rich phyllomanganate birnessite obtained by high-temperature decomposition of KMnO4 - Substructures of K-rich birnessite from 1000°C experiment, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00193628

R. Giovanoli, Vernadite is random-stacked birnessite, Mineralium Deposita, vol.15, issue.2, pp.251-253, 1980.
DOI : 10.1007/BF00206520

B. Lanson, V. A. Drits, Q. Feng, and A. Manceau, Structure of synthetic Na-birnessite: Evidence for a triclinic one-layer unit cell, American Mineralogist, vol.87, issue.11-12, pp.1662-1671, 2002.
DOI : 10.2138/am-2002-11-1215

URL : https://hal.archives-ouvertes.fr/hal-00193460

B. Lanson, V. A. Drits, A. Gaillot, E. Silvester, A. Plancon et al., Structure of heavy-metal sorbed birnessite: Part 1. Results from X-ray diffraction, American Mineralogist, vol.87, issue.11-12, 2002.
DOI : 10.2138/am-2002-11-1213

URL : https://hal.archives-ouvertes.fr/hal-00193681

Y. M. Li, R. L. Chaney, G. Siebielec, and B. A. Kerschner, Response of Four Turfgrass Cultivars to Limestone and Biosolids-Compost Amendment of a Zinc and Cadmium Contaminated Soil at Palmerton, Pennsylvania, Journal of Environment Quality, vol.29, issue.5, pp.1440-1447, 2000.
DOI : 10.2134/jeq2000.00472425002900050010x

M. Ma, P. S. Lau, Y. T. Jia, W. K. Tsang, S. K. Lam et al., The isolation and characterization of Type 1 metallothionein (MT) cDNA from a heavy-metal-tolerant plant, Festuca rubra cv. Merlin, Plant Science, vol.164, issue.1, pp.51-60, 2003.
DOI : 10.1016/S0168-9452(02)00334-5

A. Manceau and J. Combes, Structure of Mn and Fe oxides and oxyhydroxides: A topological approach by EXAFS, Physics and Chemistry of Minerals, vol.8, issue.5922, pp.283-295, 1988.
DOI : 10.1007/BF00307518

A. Manceau, V. A. Drits, E. J. Silvester, C. Bartoli, and L. B. , Structural mechanism of Co (super 2+) oxidation by the phyllomanganate buserite, American Mineralogist, vol.82, issue.11-12, pp.1150-1175, 1997.
DOI : 10.2138/am-1997-11-1213

A. Manceau, B. Lanson, V. A. Drits, D. Chateigner, W. P. Gates et al., Oxidation-reduction mechanism of iron in dioctahedral smectites: I. Crystal chemistry of oxidized reference nontronites, American Mineralogist, vol.85, issue.1, pp.133-152, 2000.
DOI : 10.2138/am-2000-0114

A. Manceau, B. Lanson, M. L. Schlegel, J. Harge, M. Musso et al., Quantitative Zn speciation in smeltercontaminated soils by EXAFS spectroscopy. Amer, J. Sci, vol.300, pp.289-343, 2000.

A. Manceau, M. A. Marcus, and N. Tamura, Quantitative Speciation of Heavy Metals in Soils and Sediments by Synchrotron X-ray Techniques, Applications of Synchrotron Radiation in Low-Temperature Geochemistry and Environmental Sciences, pp.341-428, 2002.
DOI : 10.2138/gsrmg.49.1.341

A. Manceau, M. A. Marcus, N. Tamura, O. Proux, N. Geoffroy et al., Natural speciation of Zn at the micrometer scale in a clayey soil using X-ray fluorescence, absorption, and diffraction, Geochimica et Cosmochimica Acta, vol.68, issue.11, pp.2467-2483, 2004.
DOI : 10.1016/j.gca.2003.11.021

URL : https://hal.archives-ouvertes.fr/hal-00107107

A. Manceau, C. Tommaseo, S. Rihs, N. Geoffroy, D. Chateigner et al., Natural speciation of Mn, Ni, and Zn at the micrometer scale in a clayey paddy soil using X-ray fluorescence, absorption, and diffraction, Geochimica et Cosmochimica Acta, vol.69, issue.16, pp.4007-4034, 2005.
DOI : 10.1016/j.gca.2005.03.018

URL : https://hal.archives-ouvertes.fr/hal-00160189

A. Manceau, M. Kersten, M. A. Marcus, N. Geoffroy, and L. Granina, Ba and Ni speciation in a nodule of binary Mn oxide phase composition from Lake Baikal, Geochimica et Cosmochimica Acta, vol.71, issue.8, 2007.
DOI : 10.1016/j.gca.2007.02.007

URL : https://hal.archives-ouvertes.fr/insu-00199635

A. Manceau, M. Lanson, and N. Geoffroy, Natural speciation of Ni, Zn, Ba, and As in ferromanganese coatings on quartz using X-ray fluorescence, absorption, and diffraction, Geochimica et Cosmochimica Acta, vol.71, issue.1, pp.95-128, 2007.
DOI : 10.1016/j.gca.2006.08.036

URL : https://hal.archives-ouvertes.fr/insu-00199642

K. W. Mandernack, J. Post, and T. B. , Manganese mineral formation by bacterial spores of the marine Bacillus, strain SG-1: Evidence for the direct oxidation of Mn(II) to Mn(IV), Geochimica et Cosmochimica Acta, vol.59, issue.21, pp.4393-4408, 1995.
DOI : 10.1016/0016-7037(95)00298-E

M. A. Marcus, A. A. Macdowell, R. Celestre, A. Manceau, T. Miller et al., Beamline 10.3.2 at ALS: a hard X-ray microprobe for environmental and materials sciences, Journal of Synchrotron Radiation, vol.11, issue.3, pp.239-247, 2004.
DOI : 10.1107/S0909049504005837

M. A. Marcus, A. Manceau, and M. Kersten, Mn, Fe, Zn and As speciation in a fast-growing ferromanganese marine nodule, Geochimica et Cosmochimica Acta, vol.68, issue.14, pp.3125-3136, 2004.
DOI : 10.1016/j.gca.2004.01.015

URL : https://hal.archives-ouvertes.fr/hal-00107097

Y. M. Nelson and L. W. Lion, Formation of Biogenic Manganese Oxides and Their Influence on the Scavenging of Toxic Trace Elements, Geochemical And Hydrological Reactivity Of Heavy Metals In Soils, pp.169-186, 2003.
DOI : 10.1201/9780203009604.ch7

M. L. Otte, J. Rozema, L. Koster, M. S. Haarsma, and R. A. Broekman, Iron plaque on roots of Aster tripolium L.: interaction with zinc uptake, New Phytologist, vol.151, issue.2, pp.309-317, 1989.
DOI : 10.1071/SR9830515

F. Panfili, Etude de l'évolution de la spéciation du zinc dans la phase solide d'un sédiment de curage contaminé induite par phytostabilisation, 2004.

F. R. Panfili, A. Manceau, G. Sarret, L. Spadini, T. Kirpichtchikova et al., The effect of phytostabilization on Zn speciation in a dredged contaminated sediment using scanning electron microscopy, X-ray fluorescence, EXAFS spectroscopy, and principal components analysis, Geochimica et Cosmochimica Acta, vol.69, issue.9, pp.2265-2284, 2005.
DOI : 10.1016/j.gca.2004.10.017

URL : https://hal.archives-ouvertes.fr/hal-00105745

A. Plançon, : a program for calculating the diffraction by disordered lamellar structures, Journal of Applied Crystallography, vol.35, issue.3, p.377, 2002.
DOI : 10.1107/S0021889802001449

V. Römheld, The role of phytosiderophores in acquisition of iron and other micronutrients in graminaceous species: An ecological approach, Plant and Soil, vol.130, issue.1-2, pp.127-134, 1991.
DOI : 10.1007/BF00011867

G. R. Rout and P. Das, Effect of metal toxicity on plant growth and metabolism: I. Zinc, 2003.
URL : https://hal.archives-ouvertes.fr/hal-00885964

I. Saratovsky, P. G. Wightman, P. A. Pasten, J. F. Gaillard, and P. K. , Manganese Oxides:?? Parallels between Abiotic and Biotic Structures, Journal of the American Chemical Society, vol.128, issue.34, pp.11188-11198, 2006.
DOI : 10.1021/ja062097g

G. Sarret, A. Manceau, D. Cuny, C. Vanhaluwyn, S. Deruelle et al., Mechanisms of Lichen Resistance to Metallic Pollution, Environmental Science & Technology, vol.32, issue.21, pp.3325-3330, 1998.
DOI : 10.1021/es970718n

G. Sarret, A. Manceau, L. Spadini, J. C. Roux, J. L. Hazemann et al., Cell Walls by EXAFS Spectroscopy, Environmental Science & Technology, vol.32, issue.11, pp.1648-1655, 1998.
DOI : 10.1021/es9709684

G. Sarret, P. Saumitou-laprade, V. Bert, O. Proux, J. L. Hazemann et al., Forms of Zinc Accumulated in the Hyperaccumulator Arabidopsis halleri, PLANT PHYSIOLOGY, vol.130, issue.4, pp.1815-1826, 2002.
DOI : 10.1104/pp.007799

URL : https://hal.archives-ouvertes.fr/hal-00212288

D. G. Schulze, T. Mccaybuis, S. R. Sutton, and D. M. Huber, -Infested Wheat Rhizospheres Probed by Micro-XANES Spectroscopy, Phytopathology, vol.85, issue.9, pp.990-994, 1995.
DOI : 10.1094/Phyto-85-990

URL : https://hal.archives-ouvertes.fr/hal-00757049

E. J. Silvester, A. Manceau, and D. V. , Structure of synthetic monoclinic Na-rich birnessite and hexagonal birnessite; II, Results from chemical studies and EXAFS spectroscopy, American Mineralogist, vol.82, issue.9-10, pp.962-978, 1997.
DOI : 10.2138/am-1997-9-1013

L. Simon, Stabilization of metals in acidic mine spoil with amendments and red fescue (Festuca rubra L.) growth, Environmental Geochemistry and Health, vol.29, issue.4, pp.289-300, 2005.
DOI : 10.1007/s10653-004-5977-5

R. A. Smith and A. D. Bradshaw, Stabilization of toxic mine wastes by the use of tolerant plant populations, Trans. Inst. Min. Metall, vol.81, pp.230-237, 1992.

L. St-cyr and P. Campbell, Metals (Fe, Mn, Zn) in the root plaque of submerged aquatic plants collected in situ: Relations with metal concentrations in the adjacent sediments and in the root tissue, Biogeochemistry, vol.33, issue.1, pp.45-76, 1996.
DOI : 10.1007/BF00000969

Y. Tani, N. Miyata, K. Iwahori, M. Soma, S. Tokuda et al., Biogeochemistry of manganese oxide coatings on pebble surfaces in the Kikukawa River System, Shizuoka, Japan, Applied Geochemistry, vol.18, issue.10, pp.1541-1554, 2003.
DOI : 10.1016/S0883-2927(03)00075-1

Y. Tani, N. Miyata, M. Ohashi, T. Ohnuki, H. Seyama et al., Interaction of inorganic arsenic with biogenic manganese oxide produced by a Mnoxidizing fungus, Environ. Sci. Technol, vol.38, pp.21-23, 2004.

B. M. Tebo, L. G. Vanwaasbergen, C. A. Francis, L. M. He, D. B. Edwards et al., Manganese oxidation by spores of the marine Bacillus sp. strain SG-1 - Application for the bioremediation of metal pollution, New Developments In Marine Biotechnology, pp.177-180, 1998.

B. M. Tebo, J. R. Bargar, B. G. Clement, G. J. Dick, K. J. Murray et al., BIOGENIC MANGANESE OXIDES: Properties and Mechanisms of Formation, Annual Review of Earth and Planetary Sciences, vol.32, issue.1, pp.287-328, 2004.
DOI : 10.1146/annurev.earth.32.101802.120213

B. K. Teo, EXAFS: basic principles and data analysis, 1986.
DOI : 10.1007/978-3-642-50031-2

I. A. Thompson, D. M. Huber, C. A. Guest, and D. G. Schulze, Fungal manganese oxidation in a reduced soil, Environmental Microbiology, vol.27, issue.9, pp.1480-1487, 2005.
DOI : 10.1097/00010694-200211000-00003

B. Toner, S. Fakra, M. Villalobos, T. Warwick, and G. Sposito, Spatially Resolved Characterization of Biogenic Manganese Oxide Production within a Bacterial Biofilm, Applied and Environmental Microbiology, vol.71, issue.3, 2005.
DOI : 10.1128/AEM.71.3.1300-1310.2005

B. Toner, A. Manceau, M. A. Marcus, D. B. Millet, and G. Sposito, Zinc Sorption by a Bacterial Biofilm, Environmental Science & Technology, vol.39, issue.21, pp.8288-8294, 2005.
DOI : 10.1021/es050528+

URL : https://hal.archives-ouvertes.fr/insu-00372779

B. Toner, A. Manceau, S. M. Webb, and G. Sposito, Zinc sorption to biogenic hexagonal-birnessite particles within a hydrated bacterial biofilm, Geochimica et Cosmochimica Acta, vol.70, issue.1, pp.27-43, 2006.
DOI : 10.1016/j.gca.2005.08.029

URL : https://hal.archives-ouvertes.fr/insu-00270308

J. Vangronsveld, F. Van-assche, and C. H. , Reclamation of a bare industrial area contaminated by non-ferrous metals: In situ metal immobilization and revegetation, Environmental Pollution, vol.87, issue.1, pp.51-59, 1995.
DOI : 10.1016/S0269-7491(99)80007-4

M. Villalobos, B. Toner, J. Bargar, and G. Sposito, Characterization of the manganese oxide produced by pseudomonas putida strain MnB1, Geochimica et Cosmochimica Acta, vol.67, issue.14, pp.2649-2662, 2003.
DOI : 10.1016/S0016-7037(03)00217-5

M. Villalobos, J. R. Bargar, and G. Sposito, Mechanisms of Pb(II) Sorption on a Biogenic Manganese Oxide, Environmental Science & Technology, vol.39, issue.2, pp.569-576, 2005.
DOI : 10.1021/es049434a

M. Villalobos, B. Lanson, A. Manceau, B. Toner, and G. Sposito, Structural model for the biogenic Mn oxide produced by Pseudomonas putida, American Mineralogist, vol.91, issue.4, pp.489-502, 2006.
DOI : 10.2138/am.2006.1925

URL : https://hal.archives-ouvertes.fr/hal-00193592

A. D. Wadsley, The crystal structure of chalcophanite, ZnMn3O7.3H2O, Acta Crystallographica, vol.8, issue.3, pp.165-172, 1955.
DOI : 10.1107/S0365110X55000613

B. E. Warren, X-Ray Diffraction in Random Layer Lattices, Physical Review, vol.59, issue.9, pp.693-698, 1941.
DOI : 10.1103/PhysRev.59.693

S. M. Webb, B. M. Tebo, and J. R. Bargar, Structural characterization of biogenic Mn oxides produced in seawater by the marine bacillus sp. strain SG-1, American Mineralogist, vol.90, issue.8-9, pp.1342-1357, 2005.
DOI : 10.2138/am.2005.1669

S. M. Webb, B. M. Tebo, and J. R. Bargar, Sp., Strain SG-1, Geomicrobiology Journal, vol.82, issue.3-4, pp.181-193, 2005.
DOI : 10.1021/es049434a

URL : https://hal.archives-ouvertes.fr/hal-00484167